WORLD HEALTH ALLIANCE INTERNATIONAL
World Health Alliance

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NEWS FLASH!!!
We've Joined the World Health Organization Household Water Treatment Network

World Health Alliance Interntational belongs to the World Health Organization's (International Network to promote household water treatment and safe storage) through the world in areas that household water is at risk.

 


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Background

First Aid Kit
Introduction:

The anti-microbial activity (oligodynamic action) of small quantities of metals, recognized since the nineteenth century, has been the basis for the development of many anti-microbial processes and related products. More recently, silver has been utilized for topical applications, and 1 to 3% silver sulfadiazine cream is used worldwide to prevent the infection of burn wounds and to treat post-infection skin conditions.

 

12.106 Silver

Silver occurs naturally mainly in the form of its very insoluble and immobile oxides,

sulfides and some salts. It has occasionally been found in groundwater, surface water

and drinking-water at concentrations above 5mg/litre. Levels in drinking-water

treated with silver for disinfection may be above 50mg/litre. Recent estimates of daily

intake is about 7mg per person.

Only a small percentage of silver is absorbed. Retention rates in humans and laboratory

animals range between 0 and 10%.

The only obvious sign of silver overload is argyria, a condition in which skin and

hair is heavily discolored by silver in the tissues. An oral NOAEL for argyria in

humans for a total lifetime intake of 10 g of silver was estimated on the basis of human

case reports and long-term animal experiments.

The low levels of silver in drinking-water, generally below 5mg/litre, are not relevant

to human health with respect to argyria. On the other hand, special situations

exist where silver salts may be used to maintain the bacteriological quality of

drinking-water. Higher levels of silver, up to 0.1 mg/liter (this concentration gives a

total dose over 70 years of half the human NOAEL of 10 g), could be tolerated in such

cases without risk to health.

There are no adequate data with which to derive a health-based guideline value for

silver in drinking-water.

History of guideline development

The 1958, 1963 and 1971 WHO International Standards for Drinking-water did not

refer to silver. In the first edition of the Guidelines for Drinking-water Quality, published

in 1984, it was not considered necessary to establish a guideline value for silver

in drinking-water. No health-based guideline value for silver was proposed in the 1993

Guidelines. Where silver salts are used to maintain the bacteriological quality of

12. CHEMICAL FACT SHEETS

435

drinking-water, levels of silver up to 0.1 mg/liter can be tolerated without risk to

health.

Assessment date

The risk assessment was originally conducted in 1993. The Final Task Force Meeting

in 2003 agreed that this risk assessment be brought forward to this edition of the

Guidelines for Drinking-water Quality.

Principal reference

WHO (2003) Silver in drinking-water. Background document for preparation of

WHO Guidelines for drinking-water quality. Geneva, World Health Organization

(WHO/SDE/WSH/03.04/14).

 

European Union’s Assessment

World Health Organization (WHO) and the European Union’s Assessment of Human Consumption of Silver in Drinking Water Guidelines


Who’s Guidelines for Drinking-water Quality, set up in Geneva, 1993, and are the international reference point for standard setting and drinking-water safety.   

Element/
substance
Symbol/
formula
Normally found in fresh water/surface water/ground waterHealth based guideline by the WHO
AluminumAl  0,2 mg/l
AmmoniaNH4< 0,2 mg/l (up to 0,3 mg/l in anaerobic waters)No guideline
AntimonySb< 4 μg/l0.005 mg/l
ArsenicAs  0,01 mg/l
Asbestos    No guideline
BariumBa  0,3 mg/l
BerilliumBe< 1 μg/lNo guideline
BoronB< 1 mg/l0,3 mg/l
CadmiumCd< 1 μg/l0,003 mg/l
ChlorideCl  250 mg/l
ChromiumCr+3, Cr+6< 2 μg/l0,05 mg/l
Colour    Not mentioned
CopperCu  2 mg/l
Cyanide CN-  0,07 mg/l
Dissolved oxygenO2  No guideline
FluorideF< 1,5 mg/l (up to 10)1,5 mg/l
Hardnessmg/l CaCO3  No guideline
Hydrogen sulfideH2S  No guideline
IronFe0,5 - 50 mg/lNo guideline
LeadPb  0,01 mg/l
Manganese  Mn  0,5 mg/l
MercuryHg< 0,5 μg/l0,001 mg/l 
Molybdenum  Mb< 0,01 mg/l0,07 mg/l
Nickel  Ni< 0,02 mg/l0,02 mg/l
Nitrate and nitriteNO3, NO2  50 mg/l total nitrogen
Turbidity    Not mentioned
pH    No guideline
SeleniumSe< < 0,01 mg/l0,01 mg/l
SilverAg5 – 50 μg/lNo guideline
SodiumNa< 20 mg/l200 mg/l
SulfateSO4  500 mg/l
Inorganic tinSn  No guideline
TDS    No guideline
UraniumU  1,4 mg/l
ZincZn  3 mg/l
 
The EU standards are more recent (1998), complete and strict than the WHO standards (1993).Here is a comparative table of both WHO and EU standards:
 
  WHO standards EU standards
  1993 1998
Suspended solids No guideline Not mentioned
COD No guideline Not mentioned
BOD No guideline Not mentioned
Oxidisability   5.0 mg/l O2
Grease/oil No guideline Not mentioned
Turbidity No guideline(1) Not mentioned
pH No guideline(2) Not mentioned
Conductivity 250 micros/cm 250 micros/cm
Color No guideline(3) Not mentioned
Dissolved oxygen No guideline(4) Not mentioned
Hardness No guideline(5) Not mentioned
TDS No guideline Not mentioned
     
cations    
(positive ions)    
Aluminum (Al) 0.2 mg/l 0.2 mg/l
Ammonia (NH4) No guideline 0.50 mg/l
Antimony (Sb) 0.005 mg/l 0.005 mg/l
Arsenic (As) 0.01 mg/l 0.01 mg/l
Barium (Ba) 0.3 mg/l Not mentioned
Berillium (Be) No guideline Not mentioned
Boron (B) 0.3 mg/l 1.00 mg/l
Bromate (Br) Not mentioned 0.01 mg/l
Cadmium (Cd) 0.003 mg/l 0.005 mg/l
Chromium (Cr) 0.05 mg/l 0.05 mg/l
Copper (Cu) 2 mg/l 2.0 mg/l
Iron (Fe) No guideline(6) 0.2
Lead (Pb) 0.01 mg/l 0.01 mg/l
Manganese (Mn) 0.5 mg/l 0.05 mg/l
Mercury (Hg) 0.001 mg/l 0.001 mg/l
Molibdenum (Mo) 0.07 mg/l Not mentioned
Nickel (Ni) 0.02 mg/l 0.02 mg/l
Nitrogen (total N) 50 mg/l Not mentioned
Selenium (Se) 0.01 mg/l 0.01 mg/l
Silver (Ag) No guideline Not mentioned
Sodium (Na) 200 mg/l 200 mg/l
Tin (Sn) inorganic No guideline Not mentioned
Uranium (U) 1.4 mg/l Not mentioned
Zinc (Zn) 3 mg/l Not mentioned
     
anions    
(negative ions)    
Chloride (Cl) 250 mg/l 250 mg/l
Cyanide (CN) 0.07 mg/l 0.05 mg/l
Fluoride (F) 1.5 mg/l 1.5 mg/l
Sulfate (SO4)500 mg/l 250 mg/l
Nitrate (NO3) (See Nitrogen) 50 mg/l
Nitrite (NO2) (See Nitrogen) 0.50 mg/l
     
microbiological    
parameters    
Escherichia coliNot mentioned0 in 250 ml
Enterococci Not mentioned 0 in 250 ml
Pseudomonas    
aeruginosa Not mentioned 0 in 250 ml
Clostridium    
perfringens Not mentioned 0 in 100 ml
Coliform bacteria Not mentioned 0 in 100 ml
Colony count 22oC Not mentioned 100/ml
Colony count 37oC Not mentioned 20/ml
     
other parameters    
Acrylamide Not mentioned 0.0001 mg/l
Benzene (C6H6) Not mentioned 0.001 mg/l
Benzo(a)pyrene Not mentioned 0.00001 mg/l
Chlorine dioxide (ClO2) 0.4 mg/l  
1,2-dichloroethane Not mentioned 0.003 mg/l
Epichlorohydrin Not mentioned 0.0001 mg/l
Pesticides Not mentioned 0.0001 mg/l
Pesticides - Total Not mentioned 0.0005 mg/l
PAHs Not mentioned 0.0001 mg/l
Tetrachloroethene Not mentioned 0.01 mg/l
Trichloroethene Not mentioned 0.01 mg/l
Trihalomethanes Not mentioned 0.1 mg/l
Tritium (H3) Not mentioned 100 Bq/l
Vinyl chloride Not mentioned 0.0005 mg/l
(1) Desirable: Less than 5 NTU
(2) Desirable: 6.5-8.5
(3) Desirable: 15 mg/l Pt-Co
(4) Desirable: less than 75% of the saturation concentration 
(5) Desirable: 150-500 mg/l
(6) Desirable: 0.3 mg/l
Assessment dateThe risk assessment was originally conducted in 1993. The Final Task Force Meetingin 2003 agreed that this risk assessment be brought forward to this edition of theGuidelines for Drinking-water Quality.Principal referenceWHO (2003) Selenium in drinking-water. Background document for preparation ofWHO Guidelines for drinking-water quality. Geneva, World Health Organization(WHO/SDE/WSH/03.04/13).12.106 SilverSilver occurs naturally mainly in the form of its very insoluble and immobile oxides,sulfides and some salts. It has occasionally been found in groundwater, surface waterand drinking-water at concentrations above 5mg/litre. Levels in drinking-watertreated with silver for disinfection may be above 50mg/litre. Recent estimates of dailyintake is about 7mg per person.Only a small percentage of silver is absorbed. Retention rates in humans and laboratoryanimals range between 0 and 10%.The only obvious sign of silver overload is argyria, a condition in which skin andhair is heavily discolored by silver in the tissues. An oral NOAEL for argyria inhumans for a total lifetime intake of 10 g of silver was estimated on the basis of humancase reports and long-term animal experiments.The low levels of silver in drinking-water, generally below 5mg/litre, are not relevantto human health with respect to argyria. On the other hand, special situationsexist where silver salts may be used to maintain the bacteriological quality ofdrinking-water. Higher levels of silver, up to 0.1 mg/liter (this concentration gives atotal dose over 70 years of half the human NOAEL of 10 g), could be tolerated in suchcases without risk to health.There are no adequate data with which to derive a health-based guideline value forsilver in drinking-water.History of guideline developmentThe 1958, 1963 and 1971 WHO International Standards for Drinking-water did notrefer to silver. In the first edition of the Guidelines for Drinking-water Quality, publishedin 1984, it was not considered necessary to establish a guideline value for silverin drinking-water. No health-based guideline value for silver was proposed in the 1993Guidelines. Where silver salts are used to maintain the bacteriological quality of12. CHEMICAL FACT SHEETS435drinking-water, levels of silver up to 0.1 mg/liter can be tolerated without risk tohealth.Assessment dateThe risk assessment was originally conducted in 1993. The Final Task Force Meetingin 2003 agreed that this risk assessment be brought forward to this edition of theGuidelines for Drinking-water Quality.Principal referenceWHO (2003) Silver in drinking-water. Background document for preparation ofWHO Guidelines for drinking-water quality. Geneva, World Health Organization(WHO/SDE/WSH/03.04/14).  

 

 



 



SilverDYNE® Colloidal Silver is obtained by a combination of a lyophilic colloid formed, and a lyophobic colloid of silver in an aqueous solution. The lyophilic colloid protects the lyophobe making coagulation in the lyophobe more difficult and causing the free silver atoms produced to become predominantly reoxidized to the ionic state.

 

 

 

 

 

SilverDYNE®is a clustered distilled water compound, with a double colloidal silver based, stable suspension, non-toxic, non chemical and non-hazardous product, that when used as directed will not only disinfect water, but can also extend the shelf life of most fruits and vegetables without any taste, smell, color, or toxicity. SilverDYNE® is unique because of the way it is engineered. It uses special clustering de-ionized water and engineering process that keeps the silver particles in suspension, for increased absorption and efficiency as well as guided particle direction for the elimination of bacteria.  We make true colloidal silver consisting of both elemental and ionic particles providing the ultimate particle surface area and an extremely high efficiency index.






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